Exploiting unique features of nanodiamonds as an advanced energy source

Resource Information

The work Exploiting unique features of nanodiamonds as an advanced energy source represents a distinct intellectual or artistic creation found in San Francisco Public Library. This resource is a combination of several types including: Work, Language Material, Books.

Label

Exploiting unique features of nanodiamonds as an advanced energy source

Statement of responsibility

William D. Mattson ..., [et al.]

Contributor

• U.S. Army Research Laboratory
• Mattson, William D

Subject

• Amorphous materials
• Atomic and molecular physics and spectroscopy
• Carbon
• Compression
• Diamonds
• Energy transfer
• Fullerenes
• Geology, Geochemistry and Mineralogy
• Hypervelocity impact
• Molecular dynamics
• Nanodiamonds
• Non-electrical Energy Conversion
• Particle collisions
• Raman spectra
• Vibration

Language

eng

Summary

We present a combined experimental and theoretical study on carbon nanodiamonds (NDs) using Raman and DAC experimentation and ab initio calculations. Our calculations confirm the surface reconstruction to a fullerene-like structure, and indicate compression of the diamond core, producing an estimated internal pressure of 50 GPa. Quantum molecular dynamics simulations of hypervelocity collisions of NDs show that upon collision, shock-induced amorphization first occurs, followed by complete disruption of the ND surface and ejection of reactive particles into the vacuum. Raman spectra of oxidized ND samples at increasing pressures showed a subtle increase in the vibrational intensity of the Raman feature centered near 1335 cm-1 near 18 GPa and continued under subsequent pressure increases. The intensification of this vibrational feature is consistent with a thinning of the amorphous carbon outer shell, which results in greater exposure to the diamond core with increasing pressure and may be a precursor to Structural Bond Energy Release (SBER) initiation. Additionally, a nearly twofold increase in the vibrational intensity of the sp2 graphite peak centered near 1630 cm-1 in the spectra of the oxidized nanodiamond sample suggests the possibility of a sluggish partial phase transition from sp3 hybridized diamond to sp2 hybridized graphite

Member of

• ARL-TR (Aberdeen Proving Ground, Md.), 4783

Cataloging source

DTICE

Government publication

federal national government publication

Illustrations

illustrations

Index

no index present

Literary form

non fiction

Nature of contents

• dictionaries
• bibliography

Series statement

ARL-TR

Series volume

4783